1) Why does polysubstitution frequently occur with Friedel-Crafts alkylation but not with Friedel-Crafts acylation?2) If Benzene is reacted with t-butyl chloride, why is the chief disubstituted product the para rather than ortho isomer?

Answers

Answer 1

Answer:

See explanation

Explanation:

Friedel-Crafts alkylation frequently undergo polysubstitution because the process  leads to the addition of an electron donating alkyl group, which activates the benzene ring to further alkylation. The acyl group rather deactivates the ring towards electrophilic substitution.

When benzene is reacted with t-butyl chloride, the chief disubstituted product is the para rather than ortho isomer because the increased bulk of the tert-butyl group hinders attack at the ortho-sites.


Related Questions

Consider the diagram below.
What does C represent?
A) enthalpy of reaction
B) activation energy
C) activated complex
D) energy of the reactants

Answers

Answer:

A) enthalpy of reaction

Explanation:

The region C signifies the enthalpy of reaction.

This diagram is the energy profile of an endothermic reaction. In such reaction, heat is absorbed from the surrounding. At the end of the reaction, the heat of product is lesser than that of the reactants.

Enthalpy changes are heat changes accompanying a physical and chemical change. An enthalpy is the difference between the sum of the heat contents of products and sum of the heat contents of reactants.

it is indeed A) enthalpy of reaction

SOMEONE PLZ HELP!!!!

Answers

Answer:

4.22mL

Explanation:

V=m/d

v= 18.45g/4.37g/mL

Josh heated a certain amount of blue copper sulfate crystals to get 2.1 g of white copper sulfate powder and 1.4 g of water. What is most likely the mass of the blue copper sulfate that he heated and why?

Answers

Answer: The mass of blue copper sulfate is 3.5 g

Explanation:

Law of conservation of mass states that mass can neither be created nor be destroyed but it can only be transformed from one form to another form.

This also means that total mass on the reactant side must be equal to the total mass on the product side.

The chemical equation for the heating of copper sulfate crystals is:

Let the mass of blue copper sulfate be 'x' grams

We are given:

Mass of copper sulfate powder = 2.1 grams

Mass of water = 1.4 grams

Total mass on reactant side = x

Total mass on product side = (2.1 + 1.4) g

So, by applying law of conservation of mass, we get:

Hence, the mass of blue copper sulfate is 3.5 grams

Assuming that a cheese sandwich consists of 2 slices of bread and 3 slices of cheese, determine the number of whole cheese sandwiches that can be prepared from 44 slices of bread and 63 slices of cheese.

Answers

Answer:

21 is the max but with the bread ypu could make 22 if you had 3 more cheese

Problem:
[Ar]4s2
Identify the period (p) , group (g) and valence electrons block of the element

Answers

Answer:

it is Calcium (Ca)

4th period, 2nd group, 2 valence electrons


1. What 2 subatomic particles have charges? List the particle name and its charge.

Answers

Answer: Proton - positive charge (+)

Neutron - neutral charge (0)

Electron - negative charge (-)

Explanation:

Which is one way that minerals crystallize from materials dissolved in water?

from the air
from solutions that evaporate
from hot water solutions when water boils
from the soil

Answers

Answer:

the second answer its science behind it

Answer:

b

Explanation:

What two types of elements make up an Ionic bond ?

Answers

Answer:

Metals and Non-metals

Explanation:

What is the pH of a solution made by mixing 0.050 mol of NaCN with enough water to make a liter of solution

Answers

Answer:

pH = 11

Explanation:

The equilibrium of a weak base as NaCN in water is:

NaCN(aq) + H₂O(l) ⇄ OH⁻(aq) + Na⁺(aq) + HCN(aq)

And kb, the equilibrium constant, is:

Kb = [OH⁻] [HCN] / [NaCN]

Where Kb of NaCN is 2.04x10⁻⁵

In the beginning, the [NaCN] is 0.050mol / L = 0.050M.

Both [OH⁻] and [HCN] are produced from this equilibrium, and its concentration is X, that is:

2.04x10⁻⁵ = [X] [X] / [0.050M]

1.02x10⁻⁶ = X²

X = 1x10⁻³ = [OH⁻]

As pOH = - log [OH⁻]

pOH = 3.00

And pH = 14 - pOH

pH = 11

Carbonic acid, H2CO3, has two acidic hydrogens. A solution containing an unknown concentration of carbonic acid is titrated with potassium hydroxide. It requires 22.9 mL of 1.430 M KOH solution to titrate both acidic protons in 54.2 mL of the carbonic acid solution.

Required:
a. Write a balanced net ionic equation for the neutralization reaction. Include physical states.
b. Calculate the molarity of the carbonic acid solution.

Answers

Answer:

a. H₂CO₃(aq) + KOH(aq) ⇄ K₂CO₃(aq) + H₂O(l)

b. 0.603 M

Explanation:

Step 1: Write the neutralization reaction

H₂CO₃(aq) + KOH(aq) ⇄ K₂CO₃(aq) + H₂O(l)

Step 2: Calculate the reacting moles of KOH

22.9 mL of 1.430 M KOH react.

0.0229 L × (1.430 mol/L) = 0.0327 mol

Step 3: Calculate the reacting moles of H₂CO₃

The molar ratio of H₂CO₃ to KOH is 1:1. The reacting moles of H₂CO₃ are 1/1 × 0.0327 mol = 0.0327 mol.

Step 4: Calculate the molarity of H₂CO₃

0.0327 moles of H₂CO₃ are in a volume of 54.2 mL. The molarity of H₂CO₃ is:

M = 0.0327 mol/0.0542 L = 0.603 M

Help, 8th grade Science

Answers

It’s for sure control container

Question 1 of 10

What is technology?

A. An understanding of something new.

B. The steps that engineers go through to create a product.

C. Something created using science for use by society.

D. A method that is used to solve problems,

SUBMIT

Answers

Answer:

C.

Explanation:

You can use the series of elimination for this. First, you look at A. Technology is not an understanding of something new, so we cross that out. Second, you look at B. Technology isn't a series of steps, so we can mark that one off. Third, you look at C. Technology is something created using science for use by society, so we can keep that in mind. Lastly, we check D. Technology doesn't match up to the definition, so we can cross that one out. The answer that would make the most sense would be D.

Measurements show that unknown compound X has the following composition: element mass % carbon 41.0% hydrogen 4.58% oxygen 54.6% Write the empirical chemical formula of X.

Answers

Answer:

CHO

Explanation:

Carbon = 41%,  Hydrogen = 4.58%, oxygen = 54.6%

Step 1:

Divide through by their respective relative atomic masses

41/ 12,         4.58/1,         54.6/16

3.41              4.58            3.41

Step 2:

Divide by the lowest ratio:

3.41/3.41,      4.58/3.41,     3.41/3.41

1,                    1,                  1

Hence the empirical formula is CHO

Answer:

The empirical formula of X is C3H4O3.

Explanation:

Which of the following rock will form if it is broken into sediment then emulsified over a long period of time?



Sedimentary rock


Magma rock


Metamorphic rock


Igneous rock

Answers

I believe the answer is A which is a sedimentary rock. I know this because a formation of clastic and organic rocks begins with the weathering, or breaking down, of the exposed rock into small fragments and emulsified.
(Let me know if I am wrong.)

2 2 6 2 6 2 10 3
1s 2s 2p 3s 3p 4s 3d 4p
=

Answers

Answer:

ARSENIC

Explanation:

It has an atomic number of 33

A balloon contains 1.1 L of gas at a pressure of 0.80 atm. How will the volume
change if the pressure is increased to 2.0 atm?

Answers

Answer:

Final volume  = 0.44 L

Explanation:

Given data:

Initial volume of balloon = 1.1 L

Initial pressure = 0.80 atm

Final volume = ?

Final pressure = 2.0 atm

Solution:

The given problem will be solved through the Boly's law,

"The volume of given amount of gas is inversely proportional to its pressure by keeping the temperature and number of moles constant"

Mathematical expression:

P₁V₁ = P₂V₂

P₁ = Initial pressure

V₁ = initial volume

P₂ = final pressure

V₂ = final volume  

Now we will put the values in formula,

P₁V₁ = P₂V₂

0.80 atm × 1.1 L = 2.0 atm × V₂

V₂ = 0.88 atm. L/ 2.0 atm

V₂ = 0.44 L

A certain chemical reaction releases of heat for each gram of reactant consumed. How can you calculate the heat produced by the consumption of of reactant? Set the math up. But don't do any of it. Just leave your answer as a math expression. Also, be sure your answer includes all the correct unit symbols.

Answers

Complete Question

The complete question is shown in the first uploaded image

Answer:

So the math expression is  

             [tex]heat  =  \frac{ 35. 7  KJ *  1900 \ gram }{ 1 \ gram }[/tex]

Explanation:

From the question we are told that

  The heat released for 1 gram of reactant consumed is  [tex]H  =  37.5 \ KJ/g [/tex]

   The mass of reactant considered is  [tex]m =  1.9 \ kg  =  1900 \  g[/tex]

So  if

             [tex]37.5 \ KJ [/tex] is produced for  1 gram

Then

              x kJ is produced for  1900 g  

=>   [tex]x  =  \frac{ 35. 7  KJ *  1900 \ gram }{ 1 \ gram }[/tex]

So the heat released is  

       [tex]heat  =  \frac{ 35. 7  KJ *  1900 \ gram }{ 1 \ gram }[/tex]

What concentration of NO−3NO3− results when 897 mL897 mL of 0.497 M NaNO30.497 M NaNO3 is mixed with 813 mL813 mL of 0.341 M Ca(NO3)2?

Answers

Answer:

Explanation:

NaNO₃  = Na⁺  + NO₃⁻¹

.497 M                 .497 M

moles of NO₃⁻¹ = .897 x .497 = .4458 moles

Ca( NO₃)₂  = Ca + 2 NO₃⁻¹

.341 M                    2 x .341 M = .682 M

moles of NO₃⁻¹ = .813 x .682 = .5544 moles

Total moles =  .4458 moles  +  .5544 moles

= 1.0002 moles

volume of solution = 897 + 813 = 1710 mL

= 1.710 L

concentration of nitrate ion = 1.0002 / 1.710 M

= .585 M

Having the same number of valence electrons means having similar chemical properties.
True or False

Answers

Answer:

True

Explanation:

Because atoms with the same number of valence electrons react in similar ways with other elements.

When you finish exercising, you are hot, tired, and sweating. After a bottle of juice, you feel a lot better. Which organ systems are working together in this scenario?

Answers

Answer:

Nervous and Excretory

Explanation:

The nervous system makes you thirsty. The integumentary system makes you sweat. the integumentary system is very similar to the Excretory system.

Nervous and Excretory systems are working together in this scenario.

The nervous system makes you thirsty. The integumentary system makes you sweat. the integumentary system is very similar to the Excretory system.

The blood flow increases, your brain is exposed to more oxygen and nutrients. Exercise also induces the release of beneficial proteins in the brain. Sweating cools the body when it becomes warm. When the body temperature rises, such as when exercising on a hot day, the dermal blood vessels dilate.The excretory system works with the endocrine system to help maintain homeostasis.

Learn more:

brainly.com/question/17342396

A student measured the masses of four different-sized blocks. The student determined that each block had a mass of 50 grams.


(There is a small block, a little bit bigger block, a big block and the biggles block)


Which block has the least density?

Answers

Answer:..

Explanation:

A bomb calorimeter with a heat capacity of 837 J∘C contains 745 g of water. It burns 2.50 g C8H18 resulting in the temperature going from 15.0∘C to 33.8∘C. What is the value of the heat transferred (in kilojoules) by the reaction from the perspective of the system?

Answers

Answer:

74.3kJ are transeferred

Explanation:

In the bomb calorimeter, the burning of C₈H₁₈ is producing heat that is been absorbed for the calorimeter and the water.

Heat absorbed calorimeter:

837J/°C * (33.8°C-15.0°C) = 15735.6J

Heat absorbed water:

C*m*ΔT

C specific heat of water (4.184J/g°C), m is mass of water (745g), and ΔT change in temperature (33.8°C - 15°C = 18.8°C)

4.184J/g°C*745g*18.8°C = 58601.1J

Heat released by the reaction:

15735.6J + 58601.1J = 74336.7J

74.3kJ are transeferred

plz help answer both will mark brainest

Answers

1st one is balanced other one i believe is not
hope that helps:)

Which type of reaction has the general formula of AB + CD → AD + CB?

synthesis
decomposition
oxidation
replacement

Answers

Answer:

The answer is D. Replacement

The given reaction has been the symbolization for replacement reaction. Thus, option D is correct.

The given general reaction has been:

[tex]\rm AB\;+\;CD\;\rightarrow\;AD\;+\;CB[/tex]

In the given reaction, there has presence of compound AB and CD. The reaction between the two results in the formulation of AD and CB. In the reaction, the B has been more attracted by C and forms bond with C by replacing D.

In the same way, A has been more attracted with D and forms bond with D replacing C.

The type of reaction in which the more reactive element replaces the less reactive element has been termed as replacement reaction. Thus, the given reaction has been the symbolization for replacement reaction. Thus, option D is correct.

For more information about replacement reaction, refer to the link:

https://brainly.com/question/8625202

How many moles of H2 are needed to produce 24 moles of NH3?

Answers

Answer:

36 mol of H2

Explanation:

The balanced equation of the reaction is given as;

3H2 + N2 --> 2NH3

From the reaction;

It takes 3 mol of H2 reacting with 1 mol  of N2 to form 2 mol of NH3

3 mol of H2 = 2 mol of NH3

x mol of H2 = 24 mol of NH3

x =  (24 * 3) / 2 = 36 mol of H2

Which profile best shows the topography alone line AD

Answers

The popo profile in the office

If you collect 5.74 mL of O 2 at 298 K and 1.00 atm over 60.0 seconds from a reaction solution of 5.08 mL, what is the initial rate of the reaction

Answers

Answer:

7.71 × 10⁻⁴ M/s

Explanation:

The initial rate of the reaction can be expressed by using the formula:

[tex]\dfrac{\Delta [O_2]}{\Delta t}[/tex]

where the number of moles of O₂ = [tex]\dfrac{PV}{RT}[/tex]

where;

Pressue P = 1.00 atm

Volume V =5.74mL =  (5.74 /1000) L

Rate R = 0.082 L atm/mol.K

Temperature = 298 K

[tex]= \dfrac{1.00 \ atm \times \dfrac{5.74 }{1000}L}{0.082 \ L \ atm/mol.K \times 298 K}[/tex]

= 2.35 × 10⁻⁴ mol

Δ[O₂] = [tex]\dfrac{moles \ produced - initial \ mole}{\dfrac{5.08 }{1000}L }[/tex]

Δ[O₂] = [tex]\dfrac{2.35 \times 10^{-4} M - 0 M}{\dfrac{5.08 }{1000}}[/tex]

Δ[O₂]  = 0.04626 M

The initial rate = [tex]\dfrac{\Delta [O_2]}{\Delta t}[/tex]

= [tex]\dfrac{0.04626}{60}[/tex]

= 7.71 × 10⁻⁴ M/s

Why does sodium chloride form a crystal lattice

Answers

Answer:

Ions of opposite charge strongly attract each other; those of like charges repel. As a result ions in an ionic compound are arranged in a particular manner.

Explanation:

Google is smart

4. Horizontal rows of the Periodic Table are called:
a, Clusters
Groups
b. Families
d) Periods

Answers

The horizontal rows in the periodic table are periods, while the vertical rows are called groups

The molar mass of gallium (Ga) is 69.72 g/mol.
Calculate the number of atoms in a 27.2 mg sample of Ga.
Write your answer in scientific notation using three significant figures.
atoms Ga

Answers

Answer:

2.35 x 10²⁰ atoms Ga

Explanation:

After converting from mg to g, use the molar mass as the unit converter to convert to moles. Then using Avogadro's number, 6.022 x 10²³ convert from moles to atoms of Ga.

[tex]27.2mgGa*\frac{1g}{1000mg} *\frac{1 mol Ga}{69.72gGa} *\frac{6.022*10^2^3 atoms Ga}{1 molGa} = 2.349 * 10^2^0 atoms Ga[/tex]

Then round to 3 significant figures = 2.35 x 10²⁰ atoms Ga.

The number of atoms in 27.2 mg sample of Ga is 2.35 × 10²⁰ atoms

Stoichiometry

From the question, we are to calculate the number of atoms in a 27.2 mg sample of Ga.

First, we will determine the number of moles of Ga present

Using the formula,

[tex]Number\ of\ moles = \frac{Mass}{Molar\ mass} [/tex]

Mass = 27.2 mg = 0.0272 g

Molar mass = 69.72 g/mol

Then,

[tex]Number\ of\ moles \ of\ Ga = \frac{0.0272}{69.72} [/tex]

[tex]Number\ of\ moles \ of\ Ga = [/tex] 0.000390132 moles

Now, for the number of atoms present

From the formula

Number of atoms = Number of moles × Avogadro's constant

Then,

Number of Ga atoms = 0.000390132 × 6.022×10²³

Number of Ga atoms = 2.35 × 10²⁰ atoms

Hence, the number of atoms in 27.2 mg sample of Ga is 2.35 × 10²⁰ atoms

Learn more on stoichiometry here: https://brainly.com/question/14464650

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